Uranium

Uranium

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Quotes: 
"Marie [Curie] saw our research work and I will never forget the expression of intense joy which came over her when Irene and I showed her the first artificially radioactive element in a little glass tube. I can still see her taking in her fingers (which were already burnt and swollen from radium) this little tube containing the radioactive compound - as yet one in which the activity was very weak. To verify what we had told her she held it near a Geiger-Müller counter and she could hear the rate meter giving off a great many "clicks". This was doubtless the last great satisfaction of her life." - Frederic and Irene Joliot-Curie
"If the thickness is larger than the critical value....I can produce an explosion." - Leo Szilard; early patent amendment; July 1934.
"Since the neutron carries no charge, there is no strong electrical repulsion to prevent its entry into the nucleus. In fact, the forces of attraction which hold nuclei together may actually pull the neutron into the nucleus. When a neutron enters a nucleus, the effects are about as catastrophic as if the moon struck the earth. The nucleus is violently shaken up by the blow, especially if the collision results in the capture of the neutron. A large increase in energy occurs and must be dissipated, and this may happen in a variety of ways, all of them interesting." - I. I. Rabi; January 1934.
A billet of uranium

Once James Chadwick discovered the neutron and Niels Bohr began to explain the "nucleus" of the atom, physcists in both Europe and the United States began conducting experiments to determine the physical properties of different elements.

The experiments carried out by the Joliot-Curies in France gave the first chemical proof of artificial transmutation, "One of the most important discoveries of the century,” according to Emilio Segre in 1934. Also at this time, Leo Szilard was entertaining ideas of "chain-reactions" and even "nuclear explosions.” He envisioned neutrons being much more productive than alpha particles, such as the Joliot-Curies had used in their experiments. He intuitively felt that some elements should emit two or more neutrons for each neutron captured.

 

Neutron Capture

Italian physicist Enrico Fermi began experimenting with bombarding neutrons to generate radioactivity in 1934. He started with water and the lightest elements, but had little success until he reached fluorine. From that point forward, he and his team (Segre, Edoardo Amaldi and Franco Rasetti) were able to induce radioactivity in several elements, including iron, silicon, titanium, zinc, bromine, and lanthanum.

Enrico Fermi

Fermi's team discovered that when light elements were bombarded, they generally shed a proton or alpha particle and became even lighter. But heavier elements, due to a stronger electrical barrier around the nucleus, got heavier by capturing the bombarding neutron and releasing its binding energy through gamma radiation. These elements tended to become heavier isotopes of themselves. When Fermi's group bombarded uranium, they realized that they first generated a heavier isotope, uranium-239, but then what appered to a new element, with atomic number 93. However, this initial success soon collided with prior theory, and several "mysterious" results began to take shape. It was very confusing!

In October 1934, Fermi made a startling discovery. In his own words:

"I will tell you how I came to make the discovery which I suppose is the most important one I have made. We were working very hard on the neutron induced radioactivity and the results we were obtaining made no sense. One day, as I came into the laboratory, it occurred to me that I should examine the effect of placing a piece of lead before the incident neutrons. Instead of my usual custom, I took great pains to have the piece of lead precisely machined. I was clearly dissatisfied with something. I tried every excuse to postpone putting the lead in place. When finally, with some reluctance, I was going to put in its place, I all at once grabbed an odd piece of paraffin and placed it where the lead was to have been."

Using paraffin instead of lead triggered much higher levels of radioactivity. What was happening was that the paraffin was "slowing down" the speed of the neutrons, causing them to be closer to the nucleus for a longer period of time. These neutrons were then "captured."

Ida Noddack

Bohr's lab in Copenhagen followed Fermi's research closely. At Cornell, Hans Bethe wrote a paper arguing that neutron capture was rare. All of the resulting consternation resulted in Bohr visualizing his explanation of the nucleus as composed of neutrons and protons tightly clustered together. But Bohr thought the chances of being able to use nuclear energy were low. Ernest Rutherford called the idea "moonshine." Albert Einstein compared it to "shooting in the dark at scarce birds." Bohr thought it "remote" at best.

 

Noddack Articulates Fission

In 1934, German chemist Ida Noddack critiqued Fermi's research in a paper called "On Element 93." She argued that based on Joliot-Curies' prior discoveries, instead of assuming that the newly created radioelement was heavier than uranium, he ought to have compared it to all of the known elements. She also suggested that "although in the past, elements have transmuted only into their near neighbors, it is conceivable, when heavy nuclei are bombarded by neutrons, they could break into several large fragments." Noddack's paper received little recognition at the time, but she had written one of the earliest expressions of nuclear fission. Research into uranium chemistry continued.

 

 

Related Video: 

Cloudylabs cloud chamber working approx 50 min [720p]

This experiment shows uranium decaying and emitting radiation inside a cloud chamber. Video courtesy of CloudyLabs.
More Historical Resources: 
  • Richard Rhodes, The Making of the Atomic Bomb